homehome Home chatchat Notifications


Awesome chemistry experiment: the Briggs-Rauscher iodine oscillator

I recently stumbled upon this absolutely dazzling chemistry experiment, and I just had to share it. What you will see is a pretty rare reaction in chemistry – an oscillation reaction. Three clear solutions are combined, and the color gradually changes to amber. Suddenly, the whole thing goes dark blue! Then it stays blue, reverts […]

Mihai Andrei
February 28, 2012 @ 7:40 am

share Share

I recently stumbled upon this absolutely dazzling chemistry experiment, and I just had to share it. What you will see is a pretty rare reaction in chemistry – an oscillation reaction. Three clear solutions are combined, and the color gradually changes to amber. Suddenly, the whole thing goes dark blue! Then it stays blue, reverts to amber, and the whole cycle repeats again! Don’t believe me? Just take a look.

The chemical mechanism of this reaction is really complex, but the essentials rely on two different processes:

  • A (“non-radical process”): The slow consumption of free iodine by the malonic acid substrate in the presence of iodate. This process involves the intermediate production of iodide ion
  • B (“radical process”): A fast auto-catalytic process involving manganese and free radical intermediates, which converts hydrogen peroxide and iodate to free iodine and oxygen. This process also can consume iodide up to a limiting rate.

(via Wikipedia)

But here’s the catch: process B occurs only at low quantities of iodine, so this creates a loop. At first, the iodine quantity is quite low so the B process occurs, generating lots of iodine which accumulates. Meanwhile, process A becomes stronger and stronger, creating iodide from the generated iodine. At a certain point, this process overwhelms B, and the production of free iodine is stopped, but the substance is still consumed by A. After a while, the concentration becomes low enough for process B to happen again, and then the cycle repeats again. The color change you see is a result of the two processes.

share Share

Yeast in Space? Scientists Just Launched a Tiny Lab to See If We Can Create Food in Orbit

Microbes can brew food in space — a game-changer for astronauts.

This Simple Trick Can Make Your Coffee Taste Way Better, Says Physics

If you love pour-over coffee it could serve you well to change how you pour.

Scientists Found a 380-Million-Year-Old Trick in Velvet Worm Slime That Could Lead To Recyclable Bioplastic

Velvet worm slime could offer a solution to our plastic waste problem.

Earth’s Longest Volcanic Ridge May Be an Underwater Moving Hotspot

Scientists uncover surprising evidence that the Kerguelen hotspot, responsible for the 5,000-kilometer-long Ninetyeast Ridge, exhibited significant motion.

The flower from King Tut's tomb is flooding the internet but scientists say it's fake (thanks, reddit!)

The Egyptian blue lotus sold online isn't what you think. The real story behind this mythical plant is much more interesting though.

Microlightning in Water Droplets Could Have Sparked Life on Earth

New research suggests tiny electrical charges in water droplets could have fueled the chemical reactions that led to life.

Scientists Grow Diamonds at Atmospheric Pressure in Liquid Metal and It's a Game Changer

Synthetic diamonds aren't just for the deep Earth or mega high-pressure lab anymore.

What Do Ancient Egyptian Mummies Smell Like? "Woody", "Spicy" and Even "Sweet"

Scientists used an 'electronic nose' (and good old biological sniffers) to reveal the scents of ancient mummies.

Scientists Create a Material as Strong as Steel but Light as Styrofoam Using AI

Researchers create ultra-strong, lightweight carbon structures using AI and advanced manufacturing.

Scientists Crack the Secret to the Perfect Boiled Egg -- and It's Not What You Think

I mean, do you even have a mathematical model for your egg-boiling?